The canister vent valve is to release pressure built up by pumping gas.
Delete it and you will be able to pump about half a pint before it will shut off.
Don't do it.
The purge valve release's pressure that is built up while your driving.
It releases it into the intake tract/intake to be burned off in the engine.
This valve is normally closed,and only commanded open by the pcm when needed.
Your engine commands this,and know's when it does not happen.
There is a pressure transducer in the tank that tells the computer what's going on.
The computer know's when there is as little as a .020" hole in the system,and will flag it.
At keyoff,engine not running the purge valve will be closed,and yes it does need a certain amount of vacuum to enable.
Pressure buildup in the fuel tank isn't just dangerous,it will cause driveability problems and i've seen it cause fueling issues
on return system's and closed systems alike.
It also keeps these nasty fumes (emissions) from getting into the air that my kids and your kids breathe.
Don't be too surprised if you have those same fumes floating around your car while driving.
Mini truckers regularly delete these when they bodydrop/bag trucks and move their tank/fuel cell into the bed.
Most have issues from not doing it correctly.
If you do it,make sure you switch to a vented type gas cap,as yours is built for a sealed system.
Offhand,an OBDII vehicle will run it's evap tests either on a cold start (first thing in the morning) or after it has registered a
change in the sending unit of a certain percentage.
There also must be a a certain minimum amount of fuel in the tank for the cold start test to run.
So don't keep the car running while getting gas,the car will sometimes run the test during (from reading the fuel change) and flag the light.
Oh yeah,and it's a federal felony to remove those components.
Hope some of that info helps.
[This message has been edited by DefEddie (edited 08-20-2009).]