As a hobbyist who does some of his own painting my secret is to use a HVLP spray gun. Believe it or not the Harbor Freight $15.95 one works well but you need a big compressor to feed it. Now that warmer weather is approaching I try to spray in the mornings. I've achieved the smoothest finishes when the temperature is in the low 70's with about an 8" fan pattern and spraying at no more than 25-30lbs at the gun. Its really hard to spray at home without a spray booth but you can make one from sheets of clear plastic and 1 x 2 wood.
If you are using the "rattle can" route, I would think that it would be hard to get a good result.
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" THE BLACK PARALYZER" -87GT 3800SC Series III engine, custom ZZP /Frozen Boost Intercooler setup, 3.4" Pulley, Northstar TB, LS1 MAF, 3" Spintech/Hedman Exhaust, P-log Manifold, Autolite 104's, MSD wires, Custom CAI, 4T65eHD w. custom axles, Champion Radiator, S10 Brake Booster, HP Tuners VCM Suite.
"THE COLUSSUS"
87GT - ALL OUT 3.4L Turbocharged engine, Garrett Hybrid Turbo, MSD ign., modified TH125H
" ON THE LOOSE WITHOUT THE JUICE "